HL Paper 3

Nitrogen dioxide and sulfur dioxide are two air pollutants.

Both of these air pollutants also contribute to acid deposition. Outline mechanisms for the formation of \({\text{HN}}{{\text{O}}_{\text{3}}}\) and \({\text{S}}{{\text{O}}_{\text{3}}}\).




Acid deposition is a consequence of industrial processes.

State what is meant by the term acid deposition.

[1]
a.

Describe, using equations, the mechanism of acid deposition caused by the oxides of nitrogen, including their initial formation.

[3]
b.

All shellfish have a calcium carbonate shell. Discuss, including a balanced equation, the long-term effect of acid deposition on these organisms.

 

Balanced equation:

[2]
c.



The concentration of some pollutants in a city was measured over a 24 hour period. The results are shown below.

N09/4/CHEMI/HP3/ENG/TZ0/E3

Outline the cause of the increase in NO levels between 5 and 8 am.




EDTA is produced by reacting ethane-1,2-diamine with chloroethanoic acid, ClCH2COOH.

Identify the other product formed.

[1]
a.

Explain why EDTA, a chelating agent, is more effective in removing heavy metal ions from solution than monodentate ligands.

[3]
b.